against 是介词,意思是"对着,对比"。
database为先行词,其后的against which talented players may be compared in order to identify strengths and weaknesses是一个定语从句。
关系代词which代指先行词database,在该定语从句中充当介词against的宾语。
因为定语从句的语法需要,介词和关系词which一起提到从句句首。
正常句序为:
against which talented players may be compared in order to identify strengths and weaknesses
= talented players may be compared against which in order to identify strengths and weaknesses
= talented players may be compared against (the database) in order to identify strengths and weaknesses