C2(CO2)?C(N2) |
C2(NO)?C2(CO) |
故答案为:
C2(CO2)?C(N2) |
C2(NO)?C2(CO) |
(2)已知:CH4(g)+2NO2(g)═N2(g)+CO2(g)+2H2O(g)△H1=-867kJ/mol①
2NO2(g)?N2O4(g)△H2=-56.9kJ/mol②
H2O(g)=H2O(l)△H=-44.0kJ/mol③
根据盖斯定律,①-②+④×2可得CH4(g)+N2O4(g)=N2(g)+CO2(g)+2H2O(g),故△H=-867kJ/mol-(-56.9kJ/mol)+2(-44.0)kJ/mol=-898.1kJ/mol 即CH4(g)+N2O4(g)═N2(g)+2H2O(g)+CO2(g)△H=-898.1kJ/mol,
故答案为:CH4(g)+N2O4(g)═N2(g)+2H2O(g)+CO2(g)△H=-898.1kJ/mol;